It should be noted here that the substitution of LiTFSI forLiClO4could be expected to affect the reactions of polysuldesat the negative electrode surface; LiClO4, like LiNO3,isa powerful oxidising agent which may contribute to thepassivation of the negative electrode
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Coherent water has a low ionization threshold, and is thus able to generate a tension close to –100mV when associated with incoherent water. Membrane potentials could then arise from water and not necessarily from ions.
Ok, this is a seriously cool idea. But is this just that, an idea, or is there yet experimental proof?