I don't much like the premise here (preparing to strike up specific conversations with specific people) as it runs counter to the natural flow of interaction at any event (ugh 'networking event'). I do prepare though because face to face crossroads are scarce. I check who is coming that I know and would like to catch up with, I check sessions beforehand, and whether I'd like to talk to the speaker, I check for preconf meet-ups etc, and follow posts/tags about it from other attendees. That and having a set of questions and interests to guide my participation.